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38. The covalent curves in Fig. 10 are simply given by V,,, =EEL+ VLJ,with EELthe electronic energy of the excited state of NO above ground-state energy. The quenching cross-section uQ can be obtained from the crossing distance R derived from Fig. rrRZe-aR a is a correction factor resulting from the radial dependence of the electronic wavefunction. Table I11 summarizes the results. It is seen that, using a single a parameter, all calculated cross-sections agree with experimental values within a factor of 2.

Academic Press, New York, 1978, pp. 1-56. 4. (a) F. Biraben, B. Gagnac, and G. Grynberg, Phys. Rev. , 32, 643 (1974). (b) M. D. Levenson and N. Bloemberger, Phys. Rev. , 32, 645 (1974). (c) T. W. Hhsch, K. C. Harvey, G. Meisel, and A. L. Schawlow, Opt. , 11, 50 (1974). 5. R. Wallenstein and H. Zacharias, Opt. , 25, 363 (1978). 6. (a) R. Swofford and W. M. McClain, Rev. Sci. , 46, 246 (1975). (b) U. Fritzler, Ph. Kellerrand, and G. Schaak, J. Phys. , 8, 530 (1975). 7. A. J. Twarowski and D. S.

E. Curtiss, and R. B. Bird, Molecular Theory of Guses and Liquids, Wiley, New York, 1964. H. Okabe, J. Am. Chem. , 93, 7095 (1971). APPLICATION TO NITRIC OXIDE FLUORESCENCE QUENCHING 41 40. (a) G. , 1950. @) 41. 42. 43. 44. 45. 46. G. , 1966. M. B. Robin, Higher Excited States of Polyatomic Molecules, Academic Press, New York, 1975. R. E. Olson, F. T. Smith, and E. Bauer, Appl. , 10, 1848 (1971). R. A. Beyer and W. C. Lineberger, J. Chem. , 62, 4024 (1975). R. W. Nicholls, J . Res. Nail. Bur. Std.

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